Bing
Ajax  Loading... Please wait...

Carbide Defects

Our Newsletter

Carbide Defects

Common Tungsten Carbide Defects

From the book Building Superior Brazed Tools    Buy the Book

Internal

The most common and most serious problems in Carbide are internal.  Left is a well made tip that suffered impact and had only minor chipping in one corner.  Right is tip that was poorly made and failed along a fault line.  Refer to our Carbide Material Section for more information on Carbide used as Tool Tipping Material.

 common_carbide_defects-1.jpg

 common_carbide_defects-2.jpg

Why This is Important

The customer reported some chipping and breaking during grinding.  It wasn't all the time and some times it was a lot worse than others.  The carbide supplier had examined the parts and said that there was nothing wrong with them.  We received the parts and sent them to an outside source.  They polished the surface off and took pictures of the interior.  The most visible features were internal cracks.  The crack in the middle picture runs though a pinhole.  There were also pinholes without cracks.

common_carbide_defects-3.jpg 

 common_carbide_defects-4.jpg

 common_carbide_defects-5.jpg

The tips also had internal voids or holes. Finally the carbide grains were not evenly distributed in the cobalt matrix so there is a puddle of cobalt with no carbide in it. 

 common_carbide_defects-6.jpg

Explanations

The first series of photos supplied by Valenite Die and Wear Walmet Copyright © 1999-2002 and used with permission.  The remainder are from our labs. 

 why_good_carbide_is_important-21.jpg

Clusters (Cls)- Clusters are  defined as groups of three or more WC grains that are significantly larger than the average grain size. A WC cluster can be a weak spot in the carbide microstructure. Clusters are thought to form during the cooling cycle through WC crystallization. It is not completely clear what controls this crystallization but small impurities in the powder and non-uniform carbon distribution have been implicated. It is difficult, if not impossible, to avoid clusters completely. Low levels are not considered harmful to the integrity of cemented carbide parts. Large numbers of these clusters can adversely affect performance, especially where shock is involved.

 why_good_carbide_is_important-31.jpg

Binder Lakes (Blk) - Binder lakes are pools of cobalt binder in the microstructure. They are formed when melted cobalt or nickel binder flows into open pores during sintering (1345°C+). Sinter HIP'ing eliminates binder lakes by sintering at high temperatures under an inert gas pressure of approximately 700psi. The pressure forces carbide grains, along with the binder, into the open pores. Low levels of binder lakes are not considered harmful to performance, but a large number of lakes may structurally weaken a cemented carbide part.

 why_good_carbide_is_important-41.jpg

Eta Phase (Eta-1, Eta-2, Eta-3)  - Valenite's internal rating system for eta phase. Eta phase is a carbon deficient form of tungsten carbide that results in a harder, more brittle cemented carbide part. Insufficient carbon levels are generally the result of improper formulation of the carbide powder, long term exposure of unsintered parts to the atmosphere, or poor control of sintering conditions. We rate eta phase on a scale of 0 to 3. Zero indicates that no eta phase is present, eta -3 indicates the most severe level. Eta phase is generally considered to be harmful to the performance of cemented carbide parts.  With our typical 5 minute etch, the eta phase is rapidly etched leaving a void with characteristic geometric patterns.

 why_good_carbide_is_important-51.jpg

Grade Contamination: An area of a distinctly different grade in the microstructure, round to oval in shape, whose longest axis exceeds 25 microns. Cross Grade Contamination is generally the result of ineffective cleaning of powder processing equipment.  Low levels of grade contamination are not considered harmful to performance, but a large number of these areas may adversely alter the physical properties of the cemented carbide part.

Porosity

 common_carbide_defects-12.jpg

 common_carbide_defects-13.jpg

 common_carbide_defects-14.jpg

A Porosity 

B Porosity

C Porosity

A Porosity: Pores in the microstructure less than 10 microns in diameter. Rated from A01 to A08. 

B Porosity: Pores in the microstructure 10-25 microns in diameter. Rated from B00 to B08.

C Porosity:  Not true porosity. Rather, carbon porosity consists of discrete areas of graphite in the microstructure resulting from an overabundance of carbon. Rated from C00 to C08.

Free Carbon:  A term used to describe C Porosity in excess of C00

Microphotographs of Bad Material

 common_carbide_defects-15.jpg

500 x magnification

Top right shows a very large porosity.  This material looked good until it was ground.  These pores were hidden under the surface.  During grinding pores like this opened up.  The bottom two photos show cracks in the material.  These cracks were in the material as supplied.  In this case about 30% of the material broke during the initial sharpening

 common_carbide_defects-16.jpg

This is at 1500x magnification – This is a photo of the surface and the white is binder.  The small black specks in the top right photo are areas of porosity.  The bottom right photo shows a very large ‘A’ porosity about ten microns in diameter.  The bottom left photo shows uneven distribution and contamination by foreign materials. 

 common_carbide_defects-17.jpg

1500x magnification – The top left photo shows the average quality of this material.   There are at least two oversize grains of material.  The top right photo shows a very large grain of the material. The bottom two photos show ‘B’ porosity.

 common_carbide_defects-18.jpg

 common_carbide_defects-19.jpg

 common_carbide_defects-20.jpg

 Inside of a good tip 

Small regular grains, nice tight structure with no big voids 

Inside of a bad tip

Lots of porosity - these holes mean  a much weaker tip

Close up of bad tip 

Grain size is irregular which means a weaker tip and poor wear

 common_carbide_defects-21.jpg

common_carbide_defects-22.jpg 

GREEN FRACTURE: A fracture that developed before the part had been fully sintered. Green fractured surfaces are coarse when compared to hard fracture surfaces.

HARD FRACTURE: A fracture that developed after the part had been fully sintered. Hard fractured surfaces have a smooth texture and usually contain ripples or wave lines

How Bad Carbide Breaks & Wears Out Faster

Good Carbide – small, regular grains locked tightly in a matrix.

 common_carbide_defects-23.gif

Porosity & binder lakes – lots of holes create weak areas susceptible to cracking

 common_carbide_defects-24.png

Grade contamination, reground powder & other odd large pieces

 common_carbide_defects-25.png

Eta Phase – Carbon depleted which means there are areas where the grain structure is weak

 common_carbide_defects-26.gif

Bad carbide wears out much faster because the holes and weak spots direct and concentrate the forces into the carbide

 common_carbide_defects-27.png

External Problems 

Green State Problems

As part of the manufacturing process carbide has a stage where it is very soft.  This is where chipping, bending, cracking and similar damage occurs most often.  

 common_carbide_defects-28.jpg

 common_carbide_defects-29.jpg

 common_carbide_defect-30.jpg

 common_carbide_defect-31.jpg

common_carbide_defect-32.jpg 

Cracking

 common_carbide_defect-33.jpg

 common_carbide_defect-34.jpg

Any piece of carbide showing a crack should not be used.  This is also true if there is a corner knocked off.   There are two arguments.  One is that the part is acceptable if the material will be ground down anyway.  The other argument is that the force that caused the crack or loss of a corner may have created smaller cracks that are not visible and the part should not be used.   

 

Chips, edge radius and parallelism

These all looked good to naked eye inspection.  We used 30x  magnification for inspection with standard  light and black and white high contrast.  These are picture of 5 separate tips fixtured between the jaws of dial calipers.   

The gap on the right side of this tip is about 0.005” with the largest chip about 0.002”.  On the left side the gap is about 0.002” The gap is a combination of the flatness of the side, the parallelism of the sides and the radius of the edges. 

 common_carbide_defect-36.jpg

 

common_carbide_defect-37.jpg 

common_carbide_defect-38.jpg 

common_carbide_defect-39.jpg 

Chipping, Corner and Edge Radius Standards

Saw Tips Need To Be Flat And Square.  A radius of 0.001” to 0.002” is common on competitively priced production tips from good suppliers.  

common_carbide_defect-40.jpg 

common_carbide_defect-41.jpg 

Tip 1

These were taken at 30X with Proscope.  They are tips held between tweezers.  There is one edge deliberately rounded.  As near as we can tell the rest of the edges have a radius of 0.001” and maybe up to 0.002”

Tip 2

This time we set a dial caliper to 0.005” when we took the pictures.   The caliper is resting against a deliberately rounded edge.  The two edges facing you are maybe 0.001” to 0.002” 

 

 

 

 

 

 

 

 

 

 

 

 

Establishing the Standards

We used the figures of Top grind  0.015”, Face grind 0.005”and Side grind = 0.005” assuming grinding in that order.  Face view - tip is 0.150” wide.  Grind top & sides

 common_carbide_defect-42.gif

 common_carbide_defect-43.gif

 common_carbide_defect-44.gif

 common_carbide_defect-45.gif

Finding the maximum allowable radius ends up being a matter of adding the two grinding tolerances to get 0.020”. 

 common_carbide_defect-461.gif

 common_carbide_defect-471.gif

Chips On Stump Grinder Tips

These routinely come in with some chipping. I would suggest you specify these when you order them and send us a copy of the specification.  We will be happy to inspect them for you.  

I would suggest that you specify them as:

No chip larger than  0.010”  wide x 0.005” deep.

No more than 2 chip per tip

No more than 5 chipped tips per hundred

 

 common_carbide_defect-48.jpg

One chip appears to be about .180” by 0.060” and there are chips all along the edges. 

We have chips on the current tips.  The biggest chip we found was .030” x .015”

 

 common_carbide_defect-49.jpg

Measuring Cracks and Chips in Carbide

 common_carbide_defect-52.gif

 common_carbide_defect-53.jpg

Crack depth

0.014”

0.007”

 

Crack Detection and Inspection Techniques 

Visual - Naked eye, assisted by magnifying glass, low-power microscope, lamps, mirrors.  Only at places easily accessible. Detection of small cracks requires much experience.

 common_carbide_defect-54.jpg

 common_carbide_defect-55.jpg

 common_carbide_defect-56.jpg

Saw tip – naked eye

The cracks you saw at 30x

The cracks you didn’t see at 30x

Due to space limitations this is an incomplete list.   


b2b lead generation